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961.
As one of the most common and dominant species in the Southern Ocean, Antarctic krill(Euphausia superba)play a significant role in food web structure and the process of energy flow. The diet of Antarctic krill in the Prydz Bay during austral summer of 2012/2013 was investigated and the ontogenetic shift in krill diet was evaluated using the stable isotope method. The nitrogen stable isotope values(δ~(15) N) of adults((2.78±0.58)‰) were much higher than those of juveniles((1.69±0.70)‰), whereas the carbon stable isotope values(δ~(13) C) of adults(–(28.26±1.08)‰) were slightly lower than those of juveniles(–(27.48±1.35)‰). Particulate organic matter(POM)from 0, 25, and 50 m depth combined(0/25/50 m) represented phytoplankton food items. The results showed that phytoplankton food items in surface water and mesozooplankton were two essential food items for Antarctic krill in the Prydz Bay during summer. POM(0/25/50 m) contributes 56%–69% and 26%–34% to the diet of juvenile and adult krill, respectively, whereas mesozooplankton composes 13%–34% and 58%–71% of the diet of juvenile and adult krill, respectively. Thus, an ontogenetic diet shift from POM(0/25/50 m), which consists mainly of phytoplankton, to a higher trophic level diet containing mesozooplankton, was detected. The capacity for adults to consume more zooplankton food items may minimize their food competition with juveniles, which rely mostly on phytoplankton food items. This suggests "diet shift with ontogeny" which may somehow help krill keep their dietary energy budget balanced and well adapted to the Antarctic marine ecosystem as a dominant species.  相似文献   
962.
2015年夏季开展了大亚湾悬浮颗粒有机物碳(POC)、氮含量(PN)及其同位素组成的研究,结果表明,δ13CPOC和δ15NPN的变化范围分别为-25.7‰~-17.4‰和-6.3‰~10.4‰,平均值分别为-20.2‰和8.2‰。大亚湾悬浮颗粒有机物含量及其碳氮同位素组成的空间变化反映了不同有机质来源的影响:喜洲岛附近海域表现出高POC、PN、δ13CPOC和δ15NPN的特征,指征着浮游植物水华的主导贡献;东北部范和港附近海域具有高POC、PN、低δ13CPOC和高δ15NPN的特征,反映了河流/河口水生有机物的影响;湾顶白寿湾附近海域的δ13CPOC和δ15NPN出现低值,体现了陆源有机质和人类污水排放的影响。借助δ13CPOC和δ15NPN的三端元混合模型,定量出海洋自生有机质、陆源有机质、河流/河口水生有机质等3个来源的贡献平均分别为70%、13%和17%,其中海洋自生有机质是夏季大亚湾悬浮颗粒有机物的最主要来源。从这3种来源颗粒有机物含量的空间变化看,海洋自生有机质含量由湾内向湾外减少,与初级生产力的空间变化相对应;河流/河口水生有机质含量在大亚湾东北部出现高值;陆源有机质含量在表、底层出现不同态势,表层陆源有机物含量在湾中部海域最低,而底层则呈现出自湾内向湾口增加的趋势,主要受控于离岸距离和珠江冲淡水、粤东沿岸上升流输送的影响。  相似文献   
963.
The Upper Jurassic marlstones (Mikulov Fm.) and marly limestones (Falkenstein Fm.) are the main source rocks for conventional hydrocarbons in the Vienna Basin in Austria. In addition, the Mikulov Formation has been considered a potential shale gas play. In this paper, organic geochemical, petrographical and mineralogical data from both formations in borehole Staatz 1 are used to determine the source potential and its vertical variability. Additional samples from other boreholes are used to evaluate lateral trends. Deltaic sediments (Lower Quarzarenite Member) and prodelta shales (Lower Shale Member) of the Middle Jurassic Gresten Formation have been discussed as secondary sources for hydrocarbons in the Vienna Basin area and are therefore included in the present study.The Falkenstein and Mikulov formations in Staatz 1 contain up to 2.5 wt%TOC. The organic matter is dominated by algal material. Nevertheless, HI values are relative low (<400 mgHC/gTOC), a result of organic matter degradation in a dysoxic environment. Both formations hold a fair to good petroleum potential. Because of its great thickness (∼1500 m), the source potential index of the Upper Jurrasic interval is high (7.5 tHC/m2). Within the oil window, the Falkenstein and Mikulov formations will produce paraffinic-naphtenic-aromatic low wax oil with low sulfur content. Whereas vertical variations are minor, limited data from the deep overmature samples suggest that original TOC contents may have increased basinwards. Based on TOC contents (typically <2.0 wt%) and the very deep position of the maturity cut-off values for shale oil/gas production (∼4000 and 5000 m, respectively), the potential for economic recovery of unconventional petroleum is limited. The Lower Quarzarenite Member of the Middle Jurassic Gresten Formation hosts a moderate oil potential, while the Lower Shale Member is are poor source rock.  相似文献   
964.
Authigenic carbonates are frequently associated with methane cold-seep systems, which extensively occur in various geologic settings worldwide. Of interest is the relation between the fluids involved in their formation and the isotopic signals recorded in the carbonate cements. Along the Northern Apennines foothills (Italy), hydrocarbons and connate waters still seeping nowadays are believed to be the primary sources for the formation of fossil authigenic carbonate found in Plio-Pleistocene marine sediments. Four selected outcrops of dolomitic authigenic carbonates were analysed to compare signature of seeping fluids with fractionation of stable carbon and oxygen isotopes recorded in the carbonate.Along the foothills, deep methane-rich fluids spontaneously rise to the surface through mud volcanoes or are exploited in wells drilled nearby to the fossil Plio-Pleistocene authigenic carbonates. The plumbing system providing fluids to present-day cold seeps was structurally achieved in Late Miocene and Plio-Pleistocene. δ13C values of methane, which vary from −51.9 to −43.0‰ VPDB, indicate that gas composition from the deep hydrocarbon reservoirs is relatively uniform along the foothills. On the contrary, δ13C in fossil authigenic carbonates strongly varies among different areas and also within the same outcrop.The different carbon sources that fed the investigated carbonates were identified and include: thermogenic methane from the deep Miocene reservoirs, 13C-enriched CO2 derived from secondary methanogenesis and microbial methane from Pliocene successions buried in the Po Plain. The δ13C variability documented among samples from a single outcrop testifies that the authigenic carbonates might represent a record of varying biogeochemical processes in the hydrocarbon reservoirs. The sources of stable oxygen isotopes in authigenic carbonates are often ascribed to marine water. Oxygen isotopic fractionation in the dolomite cements indicates that marine pore water couldn't be the sole source of oxygen. δ18O values provide a preliminary evidence that connate waters had a role in the carbonates precipitation. The concomitant occurrence of active cold seepages and fossil record of former plumbing systems suggests that generation and migration of hydrocarbons are long-lasting and very effective processes along the Northern Apennines foothills.  相似文献   
965.
采用碳氮稳定性同位素技术分析了东海渔山列岛浅海岩礁区生物的碳氮稳定性同位素比值,研究了浅海岩礁区14种初级生产者、61种消费者的营养级。结果表明,东海渔山列岛浅海岩礁区消费者的营养级(TL)变化范围为2.000—4.760,推断东海渔山列岛浅海岩礁区生物有4个营养级;初级生产者δ~(15)N值变化范围为2.75‰—6.85‰,消费者δ~(15)N值变化范围为4.57‰—13.39‰;通过对不同生物δ~(15)N值的比较发现,各类别生物间的δ~(15)N值差异高度显著(P0.01),短滨螺(Littorina brevicula)的δ~(15)N值最低(4.57‰),中国花鲈(Lateolabrax maculatum)和黑鲷(Acanthopagrus schlegelii)的δ~(15)N值最大,分别为11.87‰和13.39‰;单因素方差分析(One-Way ANOVA)表明4类食源间δ~(15)N和δ~(13)C值差异高度显著(P0.01);食源分析表明,鱼类的贡献范围(0.00%—7.09%)最小,初级生产者的贡献范围(27.05%—57.99%)最大;比较发现不同海域同一种生物体内富集的15N量也存在差异,这也从一个侧面反映出不同海域间生物的群落结构和稳定性存在差异。  相似文献   
966.
渤海及北黄海河流悬浮颗粒碳氮同位素时空分布及源解析   总被引:2,自引:0,他引:2  
于靖  张华 《海洋科学》2017,41(5):93-102
选择流入渤海和北黄海的36条主要河流为研究对象,对比了平水期、丰水期和枯水期水体中悬浮颗粒物和河流表层沉积物的碳和氮稳定同位素的地球化学特征,并对颗粒物有机质碳和氮来源进行分析。结果表明,水体悬浮有机质碳同位素总体上表现为δ13C平水期δ13C丰水期δ13C枯水期的特点,δ15N值呈δ15N丰水期δ15N平水期δ15N枯水期的特点。渤海和北黄海的主要入海河流悬浮颗粒物有机质的来源具有明显的季节性差异,悬浮颗粒有机质碳平水期(春秋季)来源以C3植物、土壤有机质和水生藻类为主,丰水期(夏季)碳的各来源中浮游植物的贡献率明显增大,枯水期(冬季)则表现为陆源C3植物分解和水源性有机质的混合来源;悬浮颗粒态氮的来源与季节性降水量、生活污水、合成化肥及河流内源性水生植物密切相关。  相似文献   
967.
甘肃石油河流域地下水补给来源与演化特征分析   总被引:1,自引:0,他引:1  
针对石油河流域所包含的赤金盆地与花海盆地,综合利用地下水水化学指标与稳定同位素技术系统地研究了地下水的补给来源与演化规律。其中赤金盆地地下水化学演化受控于溶滤作用,方解石、白云石、石膏等不断地溶解进入低矿化度的地下水中导致Mg2++Ca2+与HCO3-+SO42-沿1∶1等量线分布;而花海盆地高矿化度地下水中的Na+与SO42-、Na+与Cl-均有较好线性关系且多数矿物饱和指数>1,表明芒硝溶解控制了地下水中主要离子成分且地下水演化过程转由蒸发浓缩作用主导。赤金、花海盆地地下水氢氧同位素沿祁连山大气降水线分布或于右下方,二者特征相似,但后者更为富集重同位素,反映研究区地下水主要补给来源为祁连山大气降水或石油河河水;此外,两盆地间水力联系紧密,前者补给后者,因此在水资源开发利用时应将两盆地作为整体进行统筹管理,避免不合理开采造成环境地质问题。  相似文献   
968.
The Antuoling Mo deposit is a major porphyry‐type deposit in the polymetallic metallogenic belt of the northern Taihang Mountains, China. The processes of mineralization in this deposit can be divided into three stages: an early quartz–pyrite stage, a middle quartz–polymetallic sulfide stage, and a late quartz–carbonate stage. Four types of primary fluid inclusions are found in the deposit: two‐phase aqueous inclusions, daughter‐mineral‐bearing multiphase inclusions, CO2–H2O inclusions, and pure CO2 inclusions. From the early to the late ore‐forming stages, the homogenization temperatures of the fluid inclusions are 300 to >500°C, 270–425°C, and 195–330°C, respectively, with salinities of up to 50.2 wt%, 5.3–47.3 wt%, and 2.2–10.4 wt% NaCl equivalent, revealing that the ore‐forming fluids changed from high temperature and high salinity to lower temperature and lower salinity. Moreover, based on the laser Raman spectra, the compositions of the fluid inclusions evolved from the NaCl–CO2–H2O to the NaCl–H2O system. The δ18OH2O and δD values of quartz in the deposit range from +3.9‰ to +7.0‰ and ?117.5‰ to ?134.2‰, respectively, reflecting the δD of local meteoric water after oxygen isotopic exchange with host rocks. The Pb isotope values of the sulfides (208Pb/204Pb, 36.320–37.428; 207Pb/204Pb, 15.210–15.495; 206Pb/204Pb, 16.366–17.822) indicate that the ore‐forming materials originated from a mixed upper mantle–lower crust source.  相似文献   
969.
The unidirectional solidification textures (UST) quartz is generally thought to form from fluids exsolved from shallow intrusions and/or magma chambers, but such an idea is still poorly constrained from the evidence of stable isotopes. In this study, we report for the first time the δ18O of quartz that shows UST from the Qulong Cu–Mo and the Yechangping Mo porphyry deposits in China. The analysis results show that the UST quartz samples from the Qulong deposit have δ18O values ranging from +6.2 ‰ to +7.6 ‰, which are similar to that of quartz phenocrysts (+6.7 ‰ to +7.8 ‰). In contrast, the UST quartz samples from the Yechangping porphyry Mo deposit yield a high δ18O value (+10.0 ‰). The δ18Owater value of Yechangping UST quartz (+8.5 ‰) is also higher than that of Qulong (+4.6 ‰ to +5.8 ‰). Hydrothermal biotite from potassic alteration and sericite from early phyllic alteration at Qulong have similar δ18O values to UST quartz, suggesting the involvement of magmatic fluids during this stage of deposit evolution.  相似文献   
970.
Liujiaping VMS (volcanic massive sulfide) deposit contains mainly copper and zinc, which is located at the Longmenshan orogenic belt of the northwestern margin of Yangtze block. The deposit is hosted in Neoproterozoic Datan terrane (composed of Datan granitoids and Liujiaping group) and is a typical, and the biggest, VMS deposit in this area. The Datan granitoids and Liujiaping group are contemporary and both parental magmas have the same genesis. The tectonic evolution history of Northwestern Yangtze is complicated. Chronology, isotope and geochemistry of the Liujiaping VMS ores and wall rocks (especially the Datan granitoids) are analyzed to restrict the tectonic progress. High‐precision secondary ion mass spectrometry (SIMS) analysis of the Datan granitoids resulted in two concordant ages, 815.5 ± 3.2 Ma and 835.5 ± 2.6 Ma, which are contemporary with the Liujiaping Cu–Zn ore and volcanics. The wall rocks are characterized by enrichment in LREE and with a weak negative anomaly of Eu. The Pb isotope data of sulfide and volcanics from the Liujiaping deposit indicate that the material source is lower crust. Together with variable negative anomalies of high strength field elements HFSE (Th, Nb, Ta, Zr, Hf, P and Ti), positive εNd (825 Ma) values (+1.8 to +3.1) and the Nd model age T2DM = 1.2–1.3 Ga, it shows that the Liujiaping deposit and wall rocks were formed by partial melting of Mesoproterozoic lower crust. Geological and geochemical characteristics of Liujiaping deposit indicate that this deposit was formed during subduction of the oceanic crust. This study clarified that that the Liujiaping deposit and the northwestern margin of the Yangtze block were part of an arc setting at ~820 Ma rather than intra‐continental rift.  相似文献   
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